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Analysis of institutional authors

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August 31, 2021
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Mechanistic studies into visible light-driven carboxylation of aryl halides/triflates by the combined use of palladium and photoredox catalysts

Publicated to: Bulletin Of The Chemical Society Of Japan. 94 (7): 1846-1853 - 2021-07-01 94(7), DOI: 10.1246/bcsj.20210151

Authors:

Toriumi, N; Shimomaki, K; Caner, J; Murata, K; Martin, R; Iwasawa, N
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Affiliations

Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Av Paisos Catalans 16, Tarragona 43007, Spain - Author
Barcelona Institute of Science and Technology (BIST) - Author
Catalan Inst Res & Adv Studies ICREA, Passeig Lluis Companys 23, Barcelona 08010, Spain - Author
Institució Catalana de Recerca i Estudis Avançats - Author
Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan - Author
Tokyo Institute of Technology - Author
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Abstract

The reaction mechanism of palladium-catalyzed visible light-driven carboxylation of aryl halides and triflates with a photoredox catalyst was examined in detail. Experimental and theoretical studies indicated that the active species for photoredox- catalyzed reduction was cationic ArPd(II)+ species to generate nucleophilic ArPd(I) or its further reduced ArPd(0)- species, which reacted with CO2 to give carboxylic acids. Hydrodehalogenated compounds, main byproducts in this carboxylation, were thought to be generated by protonation of these reduced species.
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Keywords

carbon-dioxidechloridesco2complexeselectron-transferhalidespalladiumphotoredoxreductionCarboxylationPalladiumPhotoredoxUnactivated alkyl

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal Bulletin Of The Chemical Society Of Japan due to its progression and the good impact it has achieved in recent years, according to the agency Scopus (SJR), it has become a reference in its field. In the year of publication of the work, 2021, it was in position , thus managing to position itself as a Q1 (Primer Cuartil), in the category Chemistry (Miscellaneous).

Independientemente del impacto esperado determinado por el canal de difusión, es importante destacar el impacto real observado de la propia aportación.

Según las diferentes agencias de indexación, el número de citas acumuladas por esta publicación hasta la fecha 2026-02-07:

  • WoS: 13
  • Scopus: 3
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Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2026-02-07:

  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 10 (PlumX).
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Leadership analysis of institutional authors

This work has been carried out with international collaboration, specifically with researchers from: Japan.

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